25300
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25300
Fluka
(Chloromethyl)trimethylsilane
purum, ≥98.0% (GC)
| Synonym: | (Trimethylsilyl)methyl chloride |
| CAS Number: | 2344-80-1 |
| Linear Formula: | (CH3)3SiCH2Cl |
| Molecular Weight: | 122.67 |
| Beilstein Registry Number: | 906705 |
| EC Number: | 219-058-5 |
| MDL number: | MFCD00000878 |
| PubChem Substance ID: | 24855086 |
Description
| Other Notes | Reagent for the Peterson olefination and the homologation of ketones and aldehydes via α,β-epoxysilanes, reviews 1,2; For the synthesis of allylsilanes3 |
Properties
| vapor pressure | ~25 mmHg ( 20 °C) |
| grade | purum |
| assay | ≥98.0% (GC) |
| refractive index | n |
| bp | 98-99 °C(lit.) |
| density | 0.879 g/mL at 25 °C(lit.) |
Safety
| Personal Protective Equipment | Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter |
| Hazard Codes | F,Xi |
| Risk Statements | 11-36/37/38 |
| Safety Statements | 16-26-36 |
| RIDADR | UN1993 3/PG 2 |
| WGK Germany | 3 |
| Flash Point(F) | 24.8 °F |
| Flash Point(C) | -4 °C |
References
| Cited Reference | 1. E.W. Colvin Silicon Reagents for Organic Synthesis San Diego , (1988) |
| 2. T.V. Lee et al. Tet. 45, 5877, (1989) | |
| 3. M.B. Anderson, P.L. Fuchs Synth. Commun. 17, 621, (1987) | |
| Beilstein | Beil. 4,IV,3877 |
| Fieser | Fieser 12,118 / Fieser 13,76 |
| reference | Aldrich MSDS 1, 424:C / Corp MSDS 1 (1), 813:D / FT-IR 1 (2), 1099:C / FT-IR 2 (3), 4346:A / FT-NMR 1 (3), 638:A / IR-Spectra (3), 1539:D / NMR-Reference 2 (2), 984:B / RegBook 1 (2), 2955:D / Sigma FT-IR 1 (2), 976:D / Structure Index 1, 467:B:8 / Vapor Phase 3, 1627:C |
